Chemical Modification of Teff Straw Biomass for Adsorptive Removal of Cr (VI) from Aqueous Solution: Characterization, Optimization, Kinetics, and Thermodynamic Aspects
نویسندگان
چکیده
Teff straw, a by-product of Teff, mainly available in Ethiopia, has not been studied much for biosorbent production. The present study investigated the effects modification and optimization process parameters (viz., concentration modifying agent (H3PO4 KOH), temperature, time) on Cr (VI) removal efficiency using chemically activated straw by RSM followed BBD. maximum was obtained an H3PO4-modified 92.5% with 2 M agent, 110°C, 4 h. Similarly, KOH-modified 95.2% 1.5 activating concentration, 105°C activation 3.5 h time. In addition, adsorption dosage, initial (VI), contact were investigated. attained at g contact, 75 mg/L 25°C sorption temperature. isotherm, kinetic, thermodynamic studies biosorption studied. experimental data well fitted Langmuir isotherm pseudo-second-order kinetic model higher correlation coefficient both untreated modified biosorbent. ( Δ H o , id="M2"> S id="M3"> G ) confirmed that metal ions’ onto spontaneous endothermic.
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ژورنال
عنوان ژورنال: Adsorption Science & Technology
سال: 2022
ISSN: ['2048-4038', '0263-6174']
DOI: https://doi.org/10.1155/2022/5820207